Reactions du bromotrifluoromethane en presence de zinc : trifluoromethylations dans les conditions de barbier

Reactions of bromotrifluoromethane in presence of zinc: trifluoromethylations in barbier's conditions

• Auteur / Autrice : Catherine Francese
• Direction : François Le Goffic
• Type : Thèse de doctorat
• Discipline(s) : Chimie
• Date : Soutenance en 1987
• Etablissement(s) : Paris 6

Mots clés

Mots clés libres

Chimie

Chimie organique

Halogenoalkylation

Zinc|act

Solvant aprotique

Solvant polaire

Halogenocetone

Halogenoalcool

Hydrocarbure halogene

Compose organique perhalogene

Anhydride organique

Sulfure organique

Enamine

Lactone

Halogenure sulfonyle

Heterocycle oxygene

Cycle 5 chainons

Compose bicyclique

Compose organometallique

Methane(bromo trifluoro)|ent

Acetique acide(trifluoro) ester ethylent

Exalique acide,ester ethyle|ent

Acetone(perfluoro)|fin

Pyruvique acide(trifluoro) ester ethyle|fin

Furannedione-2,5(dihydro-2,5)|ent

Sulfure(benzyl trifluoromethyl)

Methane sulfonique acide(trifluoro) chlorure|fin

Zinc(trifluoromethyl)

Dmf|sub

Pyridine|sub

Haloalkylation

Zinc

Aprotic solvent

Polar solvent

Haloketone

Haloalcohol

Halocarbon

Organic perhalocompound

Organic anhydride

Organic sulfide

Enamine

Lactone

Sulfonyl halide

Oxygen heterocycle

Five membered ring

Bicyclic compound

Organometallic compound

Résumé

Cette methode de trifluoromethylation est assez generale