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Acyloxy-3 méthylène 2 alkanoates de méthyle : préparation, transposition allylique, conversion régiosélective en amines allyliques
FR |
EN
| Auteur / Autrice : | Farid El Guemmout |
| Direction : | A. Foucaud |
| Type : | Thèse de doctorat |
| Discipline(s) : | Chimie |
| Date : | Soutenance en 1986 |
| Etablissement(s) : | Rennes 1 |
Résumé
FR
Preparation d'acyloxy-1'alkyl-2 acrylates de methyle(i). Transposition allylique de ces acrylates en milieu heterogene en presence de fluorures alcalins. Synthese regioselective d'amines allyliques secondaires et tertiaires a partir de (i). Synthese d'amines allyliques primaires a partir d'azides. Synthese des (acyloxy-1 alcene-2yl 0,0-diethyl) et (hydroxy-1 alcene-2yl 0,0-diethyl) phosphonates